STRUCTURAL AND STEREOISOMERISM and STRUCTURAL IDENTIFICATION AND POC
Subject chemistry Medium ENGLISH
Faculty VKP Sir Status AVAILABLE
Category TOPIC BASED COURSE Lecture 20
Target XI XII XIII Books QUESTION BANK ATTACHED
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Syllabus

STRUCTURAL AND STEREOISOMERISM

Definition of isomerism, Classification of isomerism, Chain isomerism, Positional isomerism.Functional isomerism, Ring-chain isomerism,  Metamerism

Introduction, Classification of stereoisomerism, Geometrical Isomerism (G.I.) G.I. in C=C system , G.I. in Ring system , G.I. due to double bond inside the ring , CummulenesG.I. in C=N system,  E/Z Nomenclature Number of geometrical Isomers, Cummulenes, Spiranes, Cycloalkylidenes, Diphenyl system, Physical properties of geometrical isomers Optical Isomerism , Plane polarised light , Chiral centre , Chirality ' Assymmetric molecules , Dissymmetric molecules , Plane of symmetry (POS), Centre of symmetry (COS)  POS, COS. Chirality, Optical activity Wedge-Dash projection fromula , Fischer–Projection formula , Absolute configuration (R/S-configuration) , CIP-Rule Enantiomers , Diastereomers , Axis of symmetry (AOS) Erythro enantiomers, Threo enatiomers, D/L- Configuration (Relative configuration) , Number of stereoisomers , Pseudo chiral carbon (PCC), Racemic mixture (or, R/S-mixture) , Polarimeter , Functioning of polarimeter , Percentage enantiomeric excess (%EE), Optical purity Optical Resolution , Tertiary amine optical activity , Optical activity in absence of chiral centre , Cummulenes , Spiranes , Cycloalkylidene, Diphenyls , Alternating axis of symmetry (AAOS) , Conformational Isomerism Conformational isomers , Newmann projection formula , Dihedral angle (DHA) , Tortional strain (T.S.) , Vander waals strain (V.S.) , Angle strain (A.S.) , Definition of conformational isomers, Conformational analysis , Sawhorse projection formula Conversion of Fischer to  Newmann, Conformational analysis of cyclohexane , Energy profile Conformational analysis of dimethyl cyclohexane

STRUCTURAL IDENTIFICATION AND POC

Structural Identification,  Degree of unsaturation (DU),  Catalytic hydrogenation H2/cat,  Monochlorination Cl2/hn
Structural Identification , Monochlorination Cl2/hv , Ozonolysis  , Reductive ozonalysis , Oxidation ozonalysis , Practical organic chemistry (POC), POC-I , Lassaigne’s test, Elemental analysis
Elemental anlaysis , Test of unsaturation, Test of terminal alkyne , Test of alcohols , Test of carbonyl compounds , Tests of aldehydes
Iodoform Test, Sodium metal test
Sodiumbicarbonate test (NaHCO3), Test of phenols and enols , Test of nitro compounds , Test of amines , Hinseberg’s test , POC-II

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