CARBONYL COMPOUND and CARBOXILIC ACID BIOMOLECULES AND POLYMER
Subject chemistry Medium ENGLISH
Faculty VKP Sir Status AVAILABLE
Category TOPIC BASED COURSE Lecture 18
Target XI XII XIII Books QUESTION BANK ATTACHED
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Syllabus

CARBONYL COMPOUND

Preparation of aldehydes & Ketones , Dehydrogenation , Hydrolysis of gem. dihalide , From dry distillation of Col. salt of fatty acid , From acid chloride (Rossenmund's) , Formylation of benzene (Gattermann Koch Ald. Synthesis) , Chemical reaction of carbonyl compound , Nucleophilic addition reaction , Addition of H2O (Formation of hydrates)
Addition of R–OH (Formation acetal/Ketal), Addition of G.R., Addition of HCN (Formation of cyanohydrin), Addition of NH3, Addition of Ammonia derivative
Addition of NaHSO3 (Sodium bisulphite) , Backmann rearrrangment , Cyclic Ketone
Condensation reaction , Aldol condensation reaction , Cross Aldol , Intramolecular Aldol reaction
Perkin condensation reaction , Classen Ester condenstion , Cross-Claisen , Intramolecular claisen (Dieckmann's reaction ) , knoevenagel reaction
Reformatsky reaction , Favorskii reaction , Cannizaro reaction
Cross Aldol , Cross Cannizaro , Intramolecular cannizaro , Tischenko reaction , Alpha-Halogenation , Haloform reaction , Iodoform test
Baeyer - Villiger Oxidation , Benzil - Benzilic acid Rearrangement , D-exchange reaction , Witting reaction , Benzoin condensation

CARBOXILIC ACID BIOMOLECULES AND POLYMER

Carboxylic acid preparation , Arndt-Eistert reaction (Homologation of acid), Chemical reactions of carboxylic acids , Hunsdiecker reaction
Decarboxylication reaction , Decarboxylation of acids by soda lime (SL), Decarboxylation by heating , Hell-Volhard-Zelinsky (HVZ) reaction , Acid derivatives , Preparation of acid derivatives , SN2 Th reaction , Esters- preparation , Type-I mechanism of esterification, Type-II mechanism of esterification
Examples of esterification, Hydrolysis of ester , Acid hydrolysis of ester and saponification , Acid amide , Hofmann Bromamide reaction , Curtius reaction , Schmidt reaction , Lossen reaction

Polymerisation , Classification of polymer , Based on source , Base on Intermolecular force of attraction , Elastromers , Fibres , Thermoplastics, Thermosettings , Polyethylene , Nylon-6, Nylon-6,6, Natural Rubber , Synthetic Rubber- Neoprene , Buna-S, Buna-N , Dacron , Low density polyethylene (LDPE)

High density polyethylene (HDPE) , Polypropylene , Poly isobutylene , Poly vinyl chloride (PVC), Poly tetrafluoro ethylene (PTFEW Tefflon) , Poly acrylonitrile (PAN or orlon), Poly styrene , Poly methyl methanacrylate (PMMA or Lucite)  or (Plexiglas or prespex), Natural Rubber- Polyisoprene , Gutta-percha, Vinylidene chloride- Vinyl chloride polymer , Lexan-Poly carbonate , Glyptal , Bakelite (or phenol- formaldehyde Resin), Melamine- formaldehyde (Melmac) , Polyurethane

Carbohydrates , definition , Classification of carbohydrates , Based on number of units , Based on water solubility , Based on reducing properties

Monosaccharides - Aldoses and Ketoses, D/L-configuration (Relative configuration) , Glucose , Cyclic hemiacetal structure of glucose , ANOMERS , EPIMERS , Haworth structure of glucose- glucopyranose structure, Formation of methyl-O-glucoside , Mutarotation, FRUTOSE , cyclic hemiacetal structure of fructose , Haworth structure of fructose- Fructofuranose structure  

SUCROSE, Inversion of sugar , Glycosidic linkage , Maltose ,Lactose , Starch , Amylose and amylopectin , Cellulose , Reaction of carbohydrates , Osazone formation of glucose and fructose

Amino acids , Types of Alpha-Amino acids (AA), Neutral Alpha-AA, Acidic Alpha-AA, Basic Alpha-AA, Zwitter ion , Iso-electric point (pI), Calculation of pI value

Peptides , Dipeptides , Peptide link, Polypeptides , Protein , Examples of Amino acids

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